|
|
(2R,6Z)-2-hydroxy-6-(hydroxymethylidene)-2,5-dimethylcyclohex-4-ene-1,3-dione + O2 + 2-oxoglutarate <=> stipitaldehyde + succinate + CO2 + H2O
|
1.14.20
|
–
|
| |
MetaCyc:
RXN-16827
|
|
|
|
stipitaldehydate + O2 + NADPH + H+ <=> Stipitatonate + NADP+ + H2O
|
1.14.13
|
–
|
| |
MetaCyc:
RXN-16831
|
|
|
|
1,6,8-trihydroxy-1H,3H-cyclohepta[c]furan-5-one + O2 + NADPH <=> stipitalide + NADP+ + H2O
|
1.14.13
|
–
|
| |
MetaCyc:
RXN-16829
|
|
|
|
stipitalide + O2 + NADPH + H+ <=> stipitaldehydate + NADP+ + H2O
|
1.14.13
|
–
|
| |
MetaCyc:
RXN-16830
|
|
|
|
stipitaldehyde + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1,6,8-trihydroxy-1H,3H-cyclohepta[c]furan-5-one + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-16828
|
|
|
|
S-adenosyl-L-methionine + acetyl-CoA + malonyl-CoA + NADPH + H+ <=> 3-methylorcinaldehyde + S-adenosyl-L-homocysteine + CoA + H2O + NADP+ + CO2
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-16825
|
|
|
|
Stipitatonate + H2O <=> stipitatate + CO2 + H+
|
4.1.1.60
stipitatonate decarboxylase
|
–
|
| |
BRENDA:
BR321;
BS1515
KEGG:
R03739
MetaCyc:
STIPITATONATE-DECARBOXYLASE-RXN
|
|
|
|
3-methylorcinaldehyde + O2 + NADPH + H+ <=> (2R,6Z)-2-hydroxy-6-(hydroxymethylidene)-2,5-dimethylcyclohex-4-ene-1,3-dione + NADP+ + H2O
|
1.14.13
|
–
|
| |
MetaCyc:
RXN-16826
|
|
